Chidi Anagonye - The Good Place
In a perfect world where Chidi could run for president, the question of should he is still up in the air. Chidi is wonderful but he can't make a decision to save his life. How will making decisions for such a large population weigh on the nation and on him? Chidi would probably combust with so much working behind any decision that he would have to make, eventually giving up because he wouldn't want to risk anything so serious.
Oliver Queen - Arrow
Oliver Queen has been through a lot in his life so far, and none of it is fitting for a future run for president. It is harmful and it only proves why he would need to stay far away from a possible run, not that he would try honestly.
The Keating Four - How To Get Away With Murder
There is too much murder and mayhem happening around this group for any of them to make it far in a presidential run. It is as if dark stuff can't stop following them, which makes for good TV but not for promising futures in politics especially when you would be in charge of an entire nation.
Hiram Lodge - Riverdale
Riverdale Season 3 was basically a long list of reasons of why Hiram should stay far away from the White House. Bad intentions is probably an understatement when it comes to him and everything he has up his sleeve.
Hitchcock and Scully - Brooklyn Nine-Nine
These two are better off being kept away from everything always. Hitchcock and Scully like sitting in their comfortable chairs and if they were to stray too far from them, things would probably become a hot mess.
Nicholas Keynes - Timeless
There is something about Nicholas, no matter how complex his story on Timeless was, that pushes him so heavily in the no pile. It wouldn't be the best way to keep him company, especially with his past.