Smallville Green Arrow
Green Arrow makes his first Smallville appearance in episode four of season six.

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https://www.youtube.com/watch?v=39qz600f7R0
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Smallville Quotes

Lois: I thought, you know, the ride would give us a chance to get past the whole kiss-and-run of it all and get to know each other better.
Clark: Better? You tell me the color of your underwear every day. What else is there to know?

Pete: She wants to kill Lana?
Clark: Worse, she wants to become Lana.